Green Synthesis and Formation of Silica Nanoparticles Based on Natural Spondias mombin Leaf Extract for Renewable Energy Materials
DOI:
https://doi.org/10.33751/helium.v6i1.37Kata Kunci:
green synthesis, silica nanoparticles, Spondias mombinAbstrak
Silica is an abundantly available material, with applications including renewable energy materials (fuel cells). Silica has been produced using natural materials (green synthesis) to form smaller and more stable particles, primarily due to the influence of secondary metabolites such as those contained in the leaf of Spondias mombin, a species of flowering plants from Lannea coromandelica (Houtt.) Merr and the family Anacardiaceae. The characteristics of silica nanoparticles obtained by green synthesis using the Spondias mombin leaf in a water fraction at 0,6 % were identified using XRD, FTIR, PSA, TGA, SEM, and TEM. Based on the XRD pattern and SEM/TEM images, the nanoparticle is amorphous and has a particle size of 20-30 nm, smaller than that of its precursor, which is 37.6 nm. There are Si-OH and Si-O-Si groups in the FTIR spectrum as an indication of the interaction between silica nanoparticles and secondary metabolites, and the zeta potential based on PSA is -45.9 mV. This indicates that silica nanoparticles have good stability and are supported by high thermal stability based on the results of the TGA analysis. This is correlated with its use as a material composite in renewable energy (fuel cells).
Referensi
I. Pangestu, D. Oky, B. Apriandanu, R. Marcony, S. Chandren, and Y. Yulizar, “Visible-light response ZnO / CuCo 2 O 4 nanocomposite : Vibrational, optical, structural, morphological, photocatalytic, and kinetic analyses,” Ceram. Int., vol. 50, no. 18PB, pp. 34321–34330, 2024, doi: 10.1016/j.ceramint.2024.06.251.
V. Handoko, A. Yusradinan, A. Nursyahid, A. Wandira, and A. P. Wulandari, “Green Synthesis Nanopartikel Perak dengan Bioreduktor Ekstrak Daun Rami (Boehmeria nivea) Melalui Iradiasi Microwave,” vol. 10, no. 1, pp. 15–21, 2022.
Y. Yulizar, E. Kusrini, D. Oky, B. Apriandanu, and N. Nurdini, “Datura metel L. Leaves extract mediated CeO 2 nanoparticles : Synthesis, characterizations, and degradation activity of DPPH radical,” Surfaces and Interfaces, vol. 19, no. January, p. 100437, 2020, doi: 10.1016/j.surfin.2020.100437.
S. Prabha, M. Lahtinen, and M. Sillanpää, “Green synthesis and characterizations of silver and gold nanoparticles using leaf extract of Rosa rugosa,” Colloids Surfaces A Physicochem. Eng. Asp., vol. 364, no. 1–3, pp. 34–41, 2010, doi: 10.1016/j.colsurfa.2010.04.023.
M. Tajbakhsh, H. Alinezhad, M. Nasrollahzadeh, and T. A. Kamali, “Green synthesis of the Ag/HZSM-5 nanocomposite by using Euphorbia heterophylla leaf extract: A recoverable catalyst for reduction of organic dyes,” J. Alloys Compd., 2016, doi: 10.1016/j.jallcom.2016.05.278.
N. Jabeen et al., “Biosynthesis and characterisation of nano- silica as potential system for carrying streptomycin at nano-scale drug delivery,” no. 1, pp. 557–561, 2017, doi: 10.1049/iet-nbt.2016.0106.
R. H. Babu, P. Yugandhar, and N. Savithramma, “Synthesis, characterization and antimicrobial studies of bio silica nanoparticles prepared from Cynodon dactylon L.: a green,” 2018.
N. K. Sethy, Z. Arif, P. K. Mishra, and P. Kumar, “Synthesis of SiO 2 nanoparticle from bamboo leaf and its incorporation in PDMS membrane to enhance its separation properties,” vol. 39, no. 7, pp. 679–687, 2019.
K. Durairaj, P. Senthilkumar, P. Velmurugan, and K. Dhamodaran, “Sol-gel mediated synthesis of silica nanoparticle from Bambusa vulgaris leaves and its environmental applications : kinetics and isotherms studies,” 2019.
R. Asst, P. Asst, and T. Xrd, “Synthesis of Silica Nanoparticles via Green Approach by Using Hot Aqueous Extract of Thuja orientalis Leaf and Their Effect on Biofilm Formation,” vol. 50, 2018.
X. Ma and N. L. H. Oh, “Preparation and Characterization of Silica / Polyamide-imide Nanocomposite Thin Films,” pp. 1846–1851, 2010, doi: 10.1007/s11671-010-9726-7.
Y. W. Mpharm et al., “Mesoporous silica nanoparticles in drug delivery and biomedical applications,” Nanomedicine Nanotechnology, Biol. Med., 2014, doi: 10.1016/j.nano.2014.09.014.
H. Kholafazad, M. Pazhuhi, and P. Pashazadeh-panahi, “Trends in Analytical Chemistry Multifunctional aptasensors based on mesoporous silica nanoparticles as an efficient platform for bioanalytical applications : Recent advances,” Trends Anal. Chem., vol. 124, p. 115778, 2020, doi: 10.1016/j.trac.2019.115778.
P. C. Njoku and M. I. Akumefula, “Phytochemical and Nutrient Evaluation of Spondias Mombin Leaves,” Pakistan J. Nutr., vol. 6, no. 6, pp. 613–615, Oct. 2007, doi: 10.3923/pjn. 2007.613.615.
A. Gorre, A. Das, and T. Jana, “Pure and Applied Chemistry Mixed matrix composite PEM with super proton conductivity developed from ionic liquid modified silica nanoparticle and polybenzimidazole,” 2022, doi: 10.1080/10601325.2022.2154677.
I. A. Rahman and V. Padavettan, “Synthesis of Silica Nanoparticles by Sol-Gel : Size-Dependent Properties, Surface Modification, and Applications in Silica-Polymer Nanocomposites — A Review,” vol. 2012, 2012, doi: 10.1155/2012/132424.
H. Ash, “Applied Sciences: The Physical and Optical Studies of Crystalline Silica Derived from the Green Synthesis of Coconut,” 2020.
H. Veisi, S. Azizi, and P. Mohammadi, “Green synthesis of the silver nanoparticles mediated by Thymbra spicata extract and its application as a heterogeneous and recyclable nanocatalyst for catalytic reduction of a variety of dyes in water,” J. Clean. Prod., 2017, doi: 10.1016/j.jclepro.2017.09.265.
A. K. Chakraborty, “Aluminosilicate formation in various mixtures of tetraethyl orthosilicate ( TEOS ) and aluminum nitrate ( ANN ),” vol. 427, pp. 109–116, 2005, doi: 10.1016/j.tca.2004.09.021.
M. Sasivarnam, A. Anbukumaran, S. Dhanasekaran, and M. M. Abomughaidv, “Rapid Green synthesis of Nano SiO2 using Bryophyllum pinnatum leaf and evaluation of physicochemical quality attributes,” pp. 1–20, 2021.
M. Danaei et al., “Impact of Particle Size and Polydispersity Index on the Clinical Applications of Lipidic Nanocarrier Systems,” pp. 1–17, 2018, doi: 10.3390/pharmaceutics10020057.
G. V. Lowry et al., “Guidance to improve the scientific value of zeta-potential measurements in nanoEHS,” Environ. Sci. Nano, vol. 3, no. 5, pp. 953–965, 2016, doi: 10.1039/c6en00136j.
F. Lufrano, V. Baglio, O. Di Blasi, P. Staiti, V. Antonucci, and A. S. Aricò, “Solid polymer electrolyte based on sulfonated polysulfone membranes and acidic silica for direct methanol fuel cells,” Solid State Ionics, vol. 216, pp. 90–94, May 2012, doi: 10.1016/j.ssi.2012.03.015.
Unduhan
Diterbitkan
Cara Mengutip
Terbitan
Bagian
Lisensi
Hak Cipta (c) 2026 Helium: Journal of Science and Applied Chemistry
Artikel ini berlisensiCreative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
